The status and proportion for trade of agricultural products are lower than other kinds of products in world value chain (GVC). Several important traits of agricultural products, such as factor-intensive features, price elasticity of demand and the nature of technical tacit, have large effects on its GVC activity. Trade barrier, quality safety and information asymmetry limit seriously the opportunity and effectiveness of agricultural products’activity in GVC. Many steps such as defining rationally orientation, selecting flexibly driving pattern and increasing orderly existential level on GVC may be taken to strengthen the participatory validity of agriculture-related enterprises in GVC.