This paper introduces the educational factors under the heterogeneous enterprise framework. We compare education as a social infrastructure with a transport infrastructure. Through the combination of infrastructure data and industrial enterprise database, we analyze the impact of the infrastructure on enterprise export. After the classification of infrastructure, the findings have changed. Different types of infrastructure have different impacts on the export of enterprises. The supply of education plays a significant role in promoting the export of enterprises. The transport infrastructure plays an unsound role in the export of enterprises. Under the framework of industrial characteristics, infrastructure supply plays an obvious role in promoting industrial export with intensive use of some type of infrastructure elements. In the regional classification, different types of infrastructure have different impacts on the export of enterprises in coastal and inland areas. Based on the empirical results, this paper puts forward some policy suggestions.